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portada Electrochemical Phenomena in the Cathode Impedance Spectrum of pem Fuel Cells: Fundamentals and Applications
Type
Physical Book
Publisher
Language
English
Pages
386
Format
Paperback
ISBN13
9780323906074
Edition No.
1

Electrochemical Phenomena in the Cathode Impedance Spectrum of pem Fuel Cells: Fundamentals and Applications

Samuel Cruz-Manzo; Paul Greenwood (Author) · Elsevier · Paperback

Electrochemical Phenomena in the Cathode Impedance Spectrum of pem Fuel Cells: Fundamentals and Applications - Samuel Cruz-Manzo; Paul Greenwood

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Synopsis "Electrochemical Phenomena in the Cathode Impedance Spectrum of pem Fuel Cells: Fundamentals and Applications"

Electrochemical Phenomena in the Cathode Impedance Spectrum of PEM Fuel Cells: Fundamentals, Modelling, and Applications establishes how the electrochemical and diffusion mechanisms of a polymer electrolyte membrane fuel cell (PEMFC) are related to electrochemical impedance spectroscopy (EIS) measurements using physics-based impedance models derived from fundamental electrode and diffusion theories. The contribution of the different phenomena occurring at the different layers comprising the cathode on the impedance response of the PEMFC is revealed through EIS-modelling analysis. The relation between EIS measurements and polarisation curves representing the performance of PEMFCs is established. Insight is gained into how the EIS response of the PEMFC changes at different operating conditions e.g. relative humidity, load demand, gas reactant stoichiometry and temperature using physics-based impedance models. The application of impedance models with EIS measurements carried out in the individual cells comprising a PEMFC stack is demonstrated, while recent modelling approaches and other impedance models reported in the literature to represent the EIS response of the PEMFC are also considered and discussed.

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