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portada Gruppentransferpolymerisation von Michael-Monomeren: Untersuchung von C1-Symmetrischen Komplexen (Bestmasters) (in German)
Type
Physical Book
Publisher
Author
Year
2016
Language
German
Pages
160
Format
Paperback
ISBN13
9783658135737
Edition No.
1
Categories

Gruppentransferpolymerisation von Michael-Monomeren: Untersuchung von C1-Symmetrischen Komplexen (Bestmasters) (in German)

Friederike Adams (Author) · Springer Spektrum · Paperback

Gruppentransferpolymerisation von Michael-Monomeren: Untersuchung von C1-Symmetrischen Komplexen (Bestmasters) (in German) - Friederike Adams

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Synopsis "Gruppentransferpolymerisation von Michael-Monomeren: Untersuchung von C1-Symmetrischen Komplexen (Bestmasters) (in German)"

Friederike Adams untersucht 2-Aminoalkoxybis(phenolat)-Lanthanoid-Komplexe in der Seltenerdmetall-katalysierten Gruppentransferpolymerisation von Michael-Monomeren. Neu entwickelte C1-symmetrische Komplexe sind dabei in der Lage, isospezifisch 2-Vinylpyridin zu polymerisieren. Mechanistische Studien über 13C-NMR-Spektroskopie zeigen, dass die Katalysatorumgebung dabei stereoregulierend wirkt. Die Autorin führt außerdem erfolgreich Studien zur C-H-Bindungsaktivierung von Heteroaromaten via σ-Bindungsmetathese durch, um effizientere Initiatoren in diese Systeme einzuführen. 

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